The crash on the A428 near Long Buckby happened at about 12.20am yesterday (Sunday, near the junction with the B5385, when a green Ford Mondeo travelling towards Rugby was in collision with a black Range Rover travelling in the opposite direction.
The driver of the Mondeo, a 25-year-old man from Rugby, was taken to University Hospital Coventry with serious injuries.
The driver of the Range Rover, a 27-year-old man from Northampton, sustained minor injuries.
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Witnesses, or anyone with information about the collision, are asked to contact the Northamptonshire Police Collision Investigation Unit on 101 or call the Drivewatch Hotline on 0800 174615.